Applied Chemistry and Chemical Education

Address: Odessa, str. Dvoryanskaya, 2, Main Building ONU

Head of the Department honored worker of Science and Technology, Doctor of Chemical Science, Professor Seifullina Inna losifovna
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Teaching staff of the department:

Марцинко Олена Едуардівна

Martsinko Elena Eduardovna
Doctor of Chemical Sciences, Professor
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Хитрич Микола Володимирович

Khitrich Nikolay Vladimirovich
Ph.D., Associate Professo
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Шматкова Наталя Володимирівна

Shmatkova Nataliya Vladimirovna
Ph.D., Associate Professor
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Савін Сергій Миколайович

Savin Sergey Nikolaevich
Ph.D., Associate Professor

Іванченко Петро Олексійович

Ivanchenko Peter Alekseevich
PhD, Associate Professor

Scientific staff:

Чебаненко Олена Анатоліївна

Chebanenko Elena Anatolevna
Ph.D., Researcher

Скороход Лариса Сергіївна

Skorohod Larisa Sergeevna
Ph.D., Researcher

Teaching and support staff:

  • Tarasyuk Marina Yurevna - Head of the Laboratory
  • Matsyuk Nataliya Ivanovna - expert
  • Berezhneva Oksana Sergeevna - expert
  • Rovnaya Nina Ivanovna - expert

Specialization of department: coordination chemistry and macromolecular compounds.

PhD students:

  • Buchko O.V.
  • Afanasenko E.V.
  • Kiose O.O.

Associate Professors of the department give courses of lectures, practical and laboratory classes for bachelors and masters of specialties:

102 Chemistry: Macromolecular compounds, Chemistry of coordination compounds, History of chemistry, Bioinorganic chemistry, Complexation in solution and methods of research, Physicochemical methods used in the research of coordination compounds, Physicochemical methods of polymer research, The structure of macromolecules and their physicochemical properties, Mechanism of the formation of macromolecules, Coordination compounds in chemistry of polymers, Supramolecular chemistry, Modern problems of organometallic chemistry, Biocoordination chemistry.

014.06 Secondary education (Chemistry): Chemistry teaching methodology, Problem solving technique, Pedagogical practice

226 Pharmacy, industrial pharmacy: Biological activity of inorganic compounds

014.05 Secondary Education (Biology and Human Health): Inorganic Chemistry

091 Biology: General and Inorganic Chemistry

103 Earth Sciences, 106 Geography, 014.07 Secondary Education (Geography): General Chemistry, Chemistry with the Basics of Geochemistry.

PhD studies:

The department suggests a postgraduate degree in the specialty 102 Chemistry. The professors of the department give the following lectures for PhD students: "Research methods, analysis and presentation of research results", "Modern achievements in science (chemistry)", "Modern polymeric materials and methods of their research", "Chemistry of coordination compounds and methods of their research".

Scientific research

The department has a scientific school "Coordination chemistry of metals with organic molecules" (head - prof. Seifullina I. I.). Staff of the Department in recent years has defended 11 PhD theses. Innovative research performed by students and young scientists of the department aims to develop the new materials (catalysts, initiators, polymers, drugs). Students take an active part in the scientific conferences of different levels in the specialty. Department continually performs the state budget themes.

Relations with Ukrainian and international organizations:

Scientific Council NAS of Ukraine on the problem "Inorganic Chemistry", Kyiv University T. G. Shevchenko University, IGIC NASU, Institute of Microbiology and Virology, National Academy of Sciences of Ukraine, Odessa and Lugansk Medical University, Institute of Organoelement Compounds RAS, Institute of General and Inorganic Chemistry RAS, Institute of Physics Rostov State University.

Publications of employees of the Department of General Chemistry and Polymers:

During the last 5 years there have been published 3 monographs, more than 88 articles in leading periodicals (37 in Scopus, Web of Science), 77 abstracts at Ukrainian and international conferences, 3 manuals, 8 guidelines, also 10 patents of Ukraine have been received.

Examples:

  1. Seifullina I. I., Martsinko E. E., Afanasenko E.V. Design and synthesis of new homo- and heterometal coordination compounds of germanium(IV) for preparation of low toxic drugs with a wide therapeutic action // Odessa National University Herald. Chemistry. - 2015. - V.20, №4. P. 6-17.
  2. SergienkoS., Martsinko E.E., Seifullina I.I., Churakov A.V., Chebanenko E.A. Synthesis and the crystal and molecular structure of the silver(I)–germanium(IV) polymeric complex with citrate anions {[Ag2Ge(HCit)2(H2O)2]∙2H2O}n // Crystallography Reports. – 2016. Vol. 61, N 2. – P. 203-208. (SCOPUS)
  3. Sergienko V.S., Chebanenko E.A., Seifullina I.I., Churakov A.V., Martsinko E.E. Synthesis and the Crystal and Molecular Structure of the Sn(IV)–Nd(III) Coordination Polymer Based on the Tartaric Acid [NdSn2{H(Tart)3} · 12H2O]n // Crystallography Reports.- 2016 - Vol. 61, No. 2.- pp. 209–215.(SCOPUS)
  4. Varbanets L.D., Nidialkova N.A., Borzova N.V., Seifullina I.I., Martsinko E.E. Chebanenko E.A. Complexes of biscitratogermanates and biscitratostanates with metals are modifiers of bacillus thuringiensis var. іsraelensis peptidases and penicillium canescens, cladosporium cladosporioides and aspergillus niger α- galactosidases activities // Biotechnologia acta. – 2016. - Vol. 9, No 3.-pp. 52-60.
  5. Seifullina I., Martsinko E., Chebanenko E., Pirozhok O., Dyakonenko V., Shishkina S. Synthesis and structural characteristics of bis(citrate)germanates(IV) (Hbipy)2[Ge(HCit)2]∙2H2O and [CuCl(bipy)2]2[Ge(HCit)2]∙8H2O // Chemistry Journal of Moldova. General, Industrial and Ecological Chemistry - - Vol. 11(2). – P. 52-57. (SCOPUS)
  6. Alexander A. Korlyukov, Natalia V. Shmatkova, Inna I. Seifullina. Understanding the structure of salicyl hydrazone metallocomplexes: crystal structure, AIM and Hirshfeld surface analysis of trichloro-(N-salicylidenebenzoylhydrazinato-N,O,O′)-tin(IV) // Structural Chemistry. – V 27. – N 1. – P. 25-36. (SCOPUS)
  7. Varbanets L.D., Kyrychenko А.N., Seifullina I.I., Shmatkova N.V, Brovarskaya О.S. , Yaroshenko L.V., Popov L.D. Рseudomonas chlororaphis subsp. aureofaciens native and modified by complexes of Ge(IV) and Sn(IV) lipopolysaccharide antiviral activity // Biotechnologia Аcta. – 2016. Т. 9, №1. С.64-70
  8. Yalovskiy G.V., Seyfullina I.I., Pavlovsky V.I., Andronati S.A., Kravtsov Kh. Synthesis, properties and molecular structure of a tin(IV) complex with 1-[(2-hydroxy-1-naphthyl) methylenehydrazino]carbonylmethyl-7-bromo-5-phenyl-1,2-dihydro-3H-1,4-benzodiazepin-2-one // Russ. J. Struct. Chem. – 2016. – Vol. 57. N 8. – P. 1780−1783. (SCOPUS)
  9. Seifullina I., Martsinko E., Chebanenko E., Afanasenko Е., Dyakonenko V., Shishkina S. Synthesis, structure and investigation of germanium(IV) and copper(II) complexes with malic acid and 1,10ʹ-phenanthroline // Chemistry Journal of Moldova. General, Industrial and Ecological Chemistry - - Vol. 12(2). – P. 28-33. (SCOPUS)
  10. Seifullina I.I., Martsinko E.E., Chebanenko E.A., Dyakonenko V.V., Shishkina S.V., Pirozhok O.V. Structure of the {[Cu2Ge(μ-Cit)2(μ-INH)2]·4H2O}n Coordination Polymer, where H4Cit is Citric Acid, INH is Isonicotinic Acid Hydrazide // Journal of Structural Chemistry. – 2018. – Vol. 59, No 1. – P. 154-159. (SCOPUS)
  11. Polyakova I.N., Sergienko V.S., Martsinko E.E., Seifullina I.I., Chebanenko E.A. 1,3-Diamino-2-Hydroxypropane-N,N,N′,N′-Tetraacetic Acid: Crystal and Molecular Structures // Russian Journal of Coordination Chemistry. – – Vol. 44, No 2. – P. 155-161. (SCOPUS)
  12. Martsinko E.E., Seifullina I.I., Chebanenko E.A., Dyakonenko V.V., Shishkina S.V., Khristova M. Synthesis and Structure of Different-Metal Different-Ligand Germanium(IV) and Cobalt(II) or Copper(II) Complexes with 1-Hydroxyethylidenediphosphonic Acid and 1,10-Phenanthroline // Russian Journal of Coordination Chemistry. – 2018. – Vol. 44, No 6. – P. 393-399. (SCOPUS)
  13. Martsinko E., Seifullina I., Chebanenko , Pirozhok O., Dyakonenko V., Shishkina S. Synthesis and crystal structure of bis(citrato)germanate and stannate with tris(phenanthroline)nickel(II) cation // Chemistry Journal of Moldova. General, Industrial and Ecological Chemistry - 2018. - Vol. 13(2). – P. 56-62. (SCOPUS)
  14. Lukianchuk V.D., Seifullina I.I., Martsinko O.E., Shevchuk O.O. Cerebroprotection by Germanium Coordination Compounds in Experimental Acute Global Brain Ischemia // International Journal of Medicine and Medical Research. – 2018. – Vol. 4. No 1. – P. 60-66
  15. Inna Seifullina, Elena Martsinko, Elena Chebanenko, Eleonora Afanasenko, Svitlana Shishkina. Supramolecular organization and structure of Cu(II) and Ni(II), 2,2′-bipyridine cations with tartratogermanate anions // Polyhedron. – 2019. – 169. – P. 261-265. https://doi.org/10.1016/j.poly.2019.04.061 (SCOPUS)
  16. Masanovets G.N, Khitrich N.V., Seifullina I.I.,. Skorokhod L.S, Shmatkova N.V., Efimov N.N, Ugolkova E.A., Vlasenko V.G., Trigub A.L., Minin V.V. Synthesis, Structure, and Properties of Copper(II) Bromide Complexes with N-Disubstituted Thiocarbamoyl-N'-cyclohexylsulfenamides // Russian Journal of Coordination Chemistry. – 2019. – Vol. 64, No 11. – P. 1424-1431. (SCOPUS)
  17. SeifullinaI., Skorokhod L.S., Pulya A.V., Efimov N.N., Ugolkova E.A., Minin V.V. Synthesis, Characteristics, and EPR Study of Mn(II) and Cu(II) Chelates with a Product of Condensation of 2-(7-Bromo-2-oxo-5-phenyl-3Н-1,4-benzodiazepin-1-yl)acetohydrazide and 2,3-Dioxoindole // Russian Journal of Coordination Chemistry. – 2019. – Vol. 64, No 11. – P. 1432-1435 doi.org/10.1134/S0036023619110160. (SCOPUS)
  18. Seifullina I.I., Martsinko E.E., Chebanenko E.A., Afanasenko E.V., Dyakonenko V.V., Shishkina S.V. Complex Formation Products in the GeO2–Tartaric Acid–CuCl2–1,10-Phenanthroline System: Syntheses and Structures // Russian Journal of Coordination Chemistry. – 2019. – Vol. 45, No 7. – P. 496-504. https://doi.org/10.1134/S107032841906006X (SCOPUS)
  19. Chebanenko E.A., Seifullina I.I., Martsinko E.E., Dyakonenko V.V., Shishkina S.V. Synthesis and Structure of Frame Xylaratogermanate Salts with Protonated Phenanthroline and Its Complexes with Fe(III) and Ni(II) as Cations // Russian Journal of Inorganic Chemistry. – 2019. – Vol. 64, No 9. – P. 1132-1137. https://doi.org/10.1134/S0036023619090043 (SCOPUS)
  20. Lukianchuk V.D., Bukhtiarova T.A., Seifullina I.I., Polishchuk E.M., Martsinko O.E., Topolnytska H.A. Pharmacokinetics of the new cerebropetector ferrum bis(citrato)germanate at the stage of its distribution to the organs in closed head injury // International Journal of Medicine and Medical Research. – 2019. – Vol. 5. No 1. – P. 58-65. DOI: https://doi.org/10.11603/ijmmr.2413-6077.2019.1.10306
  21. Savin S.N., Kiose O.O., Rudenko V.O., Lozhichevskaya T.V. Active thinners combined systems for epoxy resins // Visnyk ОNU. Chemistry. - 2019. - Т. 24, №4(72). - С. 70-79. https://doi.org/10.18524/2304-0947.2019.4(72).185543
  22. Gudzenko O.V.,Varbanets L.D., Seifullina I.I., Martsinko E.E., Pirozhok O.V., Chebanenko E. A.Germanium coordination compounds for increasing of α-L-rhamosidases activity // Biotechnologia Acta. – 2019. - Vol. 12, No 4. - P. 19-26. doi.org/10.15407/biotech12.04.019

History:

Department of Physics and chemistry of polymers and colloids was founded in 1960 at the Chemistry Department under the leadership of Professor A. I. Yurzhenko, Honored Worker of Science of USSR, a renowned expert in the field of colloid chemistry and polymer chemistry. Scientists of the department established patterns of emulsion polymerization as one of the most important ways to prepare synthetic polymers. New types of effective multifunctional peroxides as polymerization initiators were commercialized (Professor S. S. Ivanchev, since 1997 Corresponding Member of Academy of Sciences, Associate Professor V. I. Galibey, Associate Professor Y. K. Epimahov).

Since 1970, under the guidance of Associate Professor V. A. Vilshanskiy, and since 1979 - Associate Professor Y. N. Anisimov, studies nonionic surfactants as emulsifiers in emulsion polymerization processes deployed at the Department. Research initiate polymerization processes using peroxides and organometallics were continued. In 1988, the Department of Physics and chemistry of polymers and colloids was reorganized into the Department of General Chemistry and Polymers, which in 1989 led by Associate Professor A. I. Prysiazhniuk - Specialist Macromolecular Chemistry and Inorganic Chemistry (1990 - Doctor of Chemical Science, 1991 - Professor). His scientific activity was related to the development of new types of ingredients for processing high-molecular compounds based on 3d-metal complexes of a given composition.

Since 1992, the department in charge of leading specialist in the field of coordination chemistry, Professor I. I. Seifullina. Scientific activity carried out within the scientific school "Coordination Chemistry of p-, d-and f-metals with organic nitrogen- oxygen- sulfur- and phosphorus-containing molecules" and aims to the development of science and technology in the priority area "new substances and materials." Developed the concept of control of processes directed synthesis of a wide range of new complex compounds, which, unlike usual has unique properties. Received more than 200 new homogeneous- and heteronuclear complex and supramolecular compounds of germanium, tin, s-, d- and f-elements. The new functional materials were created on their basis, including biologically active substances necessary for the production of: chemical sensors’ working bodies, sensors, gas analyzers, glass in optoelectronics, as well as effector enzymes. Patented a number of pharmaceutical substances of new type with a wide range of physiological actions (Professor Seifullina I. I., Associate Professor L. S. Skorohod, Associate Professor Shmatkova N. V., Associate Professor Martsinko E. E., Associate Professor Hitrich N. V., Associate Professor Zubkov SV, Senior Researcher V. N. Tkachenko, Research Associate Dorohtey I. L.).

Research in the area of macromolecular chemistry is going on. The regularities of copolymerization of vinyl monomers and oligomer-oligomer systems, initiated by peroxides and transition metal coordination compounds. Using energy-saving technologies developed polymeric composites filled with conductive properties and high strength characteristics (Professor Anisimov Y. N., Ph.D. Savin S. N.) Created initiating systems based on high efficiency chelate - acetylacetonates and dithiocarbamates transition metals and hydroperoxides different nature for the implementation of homogeneous and heterogeneous polymerization of vinyl monomers in the moderately of low temperatures (Associate Professor P. A., Ivanchenko, Associate Professor Y. K. Epimahov, Associate Professor N. V. Khitrich).

Adress

Dvoryanskaya str., 2,Odessa, 65082
Reception: (38-048)723-52-54
Phone/fax: (38-048)723-35-15
Email: rector@onu.edu.ua

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